Work

catena-Poly[[diphenyltin(IV)]-di-μ-isothiocyanato]: an unprecedented layered coordination polymer resulting from bridging κ2 N:S thiocyanato ligands

Year: 2024

Type: article

Abstract: , comparatively long tin-nitro-gen and short tin-sulfur bonds prove that the ambidentate iso-thio-cyanate ion acts as a bridge between two neighboring, octa-hedrally coordinated tin atoms. As a result, the mol-ecules lose their individuality in favor of a layered coordination polymer that represents a new type of mol-ecular inter-actions in the structural chemistry of diorganotin(IV) dihalides/pseudohalides. The tin atom is located on a center of inversion.

Source: IUCrData

DOI: 10.1107/s2414314624010939

Authors: Ann-Kathrin Pancratz, Anne Kamrowski, Hans Reuter

Institution: Osnabrück University

Language: English

Topic: Organometallic Compounds Synthesis and Characterization

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: gold

Estimated APC paid: $300

Funder: Deutsche Forschungsgemeinschaft