Multifunctional Effect of Carbon Matrix with Sulfur Dopant Inspires Mixed Metal Sulfide as Freestanding Anode in Sodium‐Ion Batteries
Year: 2024
Type: article
Abstract: storage, metal sulfide (MS) anodes still face several challenges, including poor intrinsic electric conductivity, severe volume change along with the shuttle and dissolution effects of discharge-produced polysulfides. In this work, the mixed nickel-manganese sulfides (NiMnS) in the morphology of uniform 2D ultrathin nanosheets are derived from layered metal-organic frameworks (MOFs), where the NiS-MnS heterojunction are accommodated in carbon matrix with S dopant (NiMnS/SC). Through experiments and density functional theory (DFT) simulations, it is revealed that the carbon matrix with S dopant has multifunctional effects on active NiMnS during the charge/discharge process, including conductive intermediary, electrochemical active site, physical barrier, and chemical adsorption. This work may promote the design of MS-based electrodes in SIBs and extend the application of carbon material with S dopant in Na-S batteries.
Source: Small
Language: English
Subfield: Electrical and Electronic Engineering
Field: Engineering
Domain: Physical Sciences
Open Access status: bronze
OpenAlex ID: W4404506997