Work

Free-Standing Carbon Nanofiber Films with Supported Cobalt Phosphide Nanoparticles as Cathodes for Hydrogen Evolution Reaction in a Microbial Electrolysis Cell

Year: 2024

Type: article

Abstract: High-performance and cost-efficient electrocatalysts and electrodes are needed to improve the hydrogen evolution reaction (HER) for the hydrogen (H2) generation in electrolysers, including microbial electrolysis cells (MECs). In this study, free-standing carbon nanofiber (CNF) films with supported cobalt phosphide nanoparticles have been prepared by means of an up-scalable electrospinning process followed by a thermal treatment under controlled conditions. The produced cobalt phosphide-supported CNF films show to be nanoporous (pore volume up to 0.33 cm3 g−1) with a high surface area (up to 502 m2 g−1) and with a suitable catalyst mass loading (up to 0.49 mg cm−2). Values of overpotential less than 140 mV at 10 mA cm−2 have been reached for the HER in alkaline media (1 M KOH), which demonstrates a high activity. The high electrical conductivity together with the mechanical stability of the free-standing CNF films allowed their direct use as cathodes in a MEC reactor, resulting in an exceptionally low voltage operation (0.75 V) with a current density demand of 5.4 A m−2. This enabled the production of H2 with an energy consumption below 30 kWh kg−1 H2, which is highly efficient.

Source: Nanomaterials

DOI: 10.3390/nano14221849

Authors: Gerard Pérez-Pi, Jorge Luque-Rueda, Pau Bosch-Jimenez, Eduard Borràs Camps, Sandra Martínez-Crespiera

Institution: Leitat Technological Center

Language: English

Topic: Electrocatalysts for Energy Conversion

Subfield: Renewable Energy, Sustainability and the Environment

Field: Energy

Domain: Physical Sciences

SDG: Affordable and clean energy

Open Access status: gold

Estimated APC paid: $3,296