Subcycle resolved strong field ionization of chiral molecules and the origin of chiral photoelectron asymmetries
Year: 2024
Type: article
Abstract: We report on strong field ionization of S- and R-propylene oxide in circularly polarized two-color laser fields. We find that the relative helicity of the two single-color laser fields affects the photoelectron circular dichroism (PECD). Further, we observe that PECD is modulated as a function of the subcycle release time of the electron. Our experimental observations are successfully described by a heuristic model based on electrons in chiral initial states, which are selectively liberated by the laser field and, after tunneling, interact with an achiral Coulomb potential. Published by the American Physical Society 2024
Source: Physical Review Research
Language: English
Subfield: Atomic and Molecular Physics, and Optics
Field: Physics and Astronomy
Domain: Physical Sciences
Open Access status: gold
Estimated APC paid: $3,277
Funder: Deutsche Forschungsgemeinschaft
Award: G5103974534
OpenAlex ID: W4404534613