Work

Balancing Color and Hardness in ZnO–Al 2 O 3 –SiO 2 Glass-Ceramics by Tailoring the ZrO 2 /TiO 2 Nucleating Agents Ratio

Year: 2024

Type: article

Abstract: High Resolution Image Download MS PowerPoint Slide Transparent and hard ZnO–Al 2 O 3 –SiO 2 (ZAS) glass-ceramics (GCs) are desirable for various applications. However, TiO 2, an effective nucleating agent for this system, can introduce an unwanted yellow coloration. This study explores the effect of partially replacing TiO 2 with ZrO 2 on the crystallization pathways, color, transparency, and hardness of ZAS glasses and corresponding GCs, by evaluating compositions containing a constant content (4.5 mol %) of the referred nucleating agents. Optical transmittance showed that all glasses and GCs prepared were transparent in the visible range. However, they presented a yellowish hue that faded as the ZrO 2 /TiO 2 ratio increased, as indicated by the CIELab analyses. One possible source of such coloration is the presence of iron ions in different oxidation states such as Fe 2+ and Fe 3+, this last detected by Electron Paramagnetic Resonance measurements in all the glasses. The samples’ color is also likely affected by the Ti 4+ –O 2– charge transfer mechanism. Concerning the mechanical performance, all GCs present similar hardness, which is a consequence of the slight variation in the crystallization kinetics with the varying ZrO 2 /TiO 2 ratio. Therefore, the partial replacement of TiO 2 with ZrO 2 enables the preparation of glasses and GCs with a lighter coloration, without impairing their hardness.

Source: Crystal Growth & Design

DOI: 10.1021/acs.cgd.4c01000