Work

Synthesis of C-mercuro derivatives of ortho-carborane. Crystal structure of bis(2-phenyl-ortho-carboran-1-yl)mercury

Year: 2024

Type: article

Abstract: Many carborane derivatives, first synthesized during the rapid development of this field of chemistry in the 60s of the last century, remained completely uncharacterized by modern spectral and structural methods. In this work, a series of C-mercuro derivatives of ortho-carborane 1-PhHg-2-Ph-1,2-C2B10H10 and (2-R-1,2-C2B10H10)2Hg (R = H, Me, Ph) were newly synthesized and characterized by NMR spectroscopy. The molecular crystal structure of bis(2-phenyl-ortho-carboran-1-yl)mercury was determined by single crystal X-ray diffraction.

Source: Журнал неорганической химии

DOI: 10.31857/s0044457x24050014

Authors: S. А. Anufriev, S. V. Timofeev, D. I. Nasyrova, I. B. Sivaev, V. I. Bregadze

Institutions: Russian Academy of Sciences, A. N. Nesmeyanov Institute of Organoelement Compounds, Moscow Institute of Physics and Technology, N.D. Zelinsky Institute of Organic Chemistry, Plekhanov Russian University of Economics

Language: English

Topic: Boron Compounds in Chemistry

Subfield: Radiology, Nuclear Medicine and Imaging

Field: Medicine

Domain: Health Sciences

Open Access status: diamond

OpenAlex ID: W4404579898

FWCI:

Cites: 49

Cited by:

Related to: 10