Nanoelectronic Detection of Acetone with MIL-53(Al)−NH 2 Metal–Organic Framework on Single-Walled Carbon Nanotubes
Year: 2024
Type: article
Abstract: High Resolution Image Download MS PowerPoint Slide A new composite material has been synthesized by incorporating an amine-functionalized MIL-53 (Al) metal–organic framework (MOF) and single-walled carbon nanotubes (SWCNT) under hydrothermal conditions. This hybrid material combines the porosity of the MOF with the electrical conductivity of SWCNT. The preservation of MIL-53(Al)–NH 2 MOF structure and morphology in the composite with SWCNT was verified by X-ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy, transmission electron microscopy, and Brunauer–Emmett–Teller surface area analysis. A characteristic current–voltage ( I – V ) curve showed the electrical conductivity of this composite and gave a linear response in the chemiresistive sensor with increasing concentrations of acetone. The MIL-53(Al)–NH 2 /SWCNT composite also displayed fluorescence quenching tendencies across various acetone concentrations, likely attributable to the impact of guest molecules influencing the framework. An alternative approach utilizing layer-by-layer sensor device fabrication was employed for growing this MOF on carbon nanotubes directly onto a silicon chip, demonstrating its potential for versatile on-chip-sensing applications.
Institution: University of Pittsburgh
Language: English
Subfield: Electrical and Electronic Engineering
Field: Engineering
Domain: Physical Sciences
Open Access status: hybrid
Estimated APC paid: $4,500
Funder: University of Pittsburgh
OpenAlex ID: W4404585542