Work

P + addition and transfer involving a tetraphosphenium ion

Year: 2024

Type: article

Abstract: Formal addition of “P + ” to an electrophilic bisphosphanylphosphenium ion, results in the formation of a dicationic tetraphosphenium ion featuring a remarkably long P–P bond between trivalent P-atoms and super Lewis acidic character.

Source: Chemical Science

DOI: 10.1039/d4sc06823h

Authors: Roman Franz, Máté Bartek, Clemens Bruhn, Zsolt Kelemen, Rudolf Pietschnig

Institutions: University of Kassel, Budapest University of Technology and Economics

Language: English

Topic: Synthesis and characterization of novel inorganic/organometallic compounds

Subfield: Inorganic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: diamond

Funders: Deutsche Forschungsgemeinschaft, Hungarian Scientific Research Fund, Hungarian Science Foundation, Nemzeti Kutatási Fejlesztési és Innovációs Hivatal