Work

A Refined Set of Universal Force Field Parameters for Some Metal Nodes in Metal–Organic Frameworks

Year: 2024

Type: article

Abstract: High Resolution Image Download MS PowerPoint Slide Metal–organic frameworks (MOFs) exhibit promise as porous materials for carbon capture due to their design versatility and large pore sizes. The generic force fields (e.g., UFF and Dreiding) use one universal set of Lennard-Jones parameters for each element, while MOFs have a much richer local chemical environment than those chemical environments used to fit the UFF. When MOFs contain hard-Lewis acid metals, UFF systematically overestimates CO 2 uptakes. To address this, we developed a workflow to affordably and efficiently generate reliable force fields to predict CO 2 adsorption isotherms of MOFs containing metals from groups IIA (Mg, Ca, Sr, and Ba) and IIIA (Al, Ga, and In), connected to various carboxylate ligands. This method uses experimental isotherms as input. The optimal parameters are obtained by minimizing the loss function of the experimental and simulated isotherms, in which we use the Multistate Bennett Acceptance Ratio (MBAR) theory to derive the functionality relationship of loss functions in terms of force field parameters.

Source: Journal of Chemical Theory and Computation

DOI: 10.1021/acs.jctc.4c01113

Authors: Yutao Li, Xin Jin, Elias Moubarak, Berend Smit

Institution: École Polytechnique Fédérale de Lausanne

Language: English

Topic: Metal-Organic Frameworks: Synthesis and Applications

Subfield: Inorganic Chemistry

Field: Chemistry

Domain: Physical Sciences

SDG: Climate action

Open Access status: hybrid

Estimated APC paid: $4,500