Work

Pivotal role of solid phase interactions in the pressure-induced bi-stability of cyanide-bridged Fe 2 Co 2 square complexes

Year: 2024

Type: article

Abstract: Pressure-sensitive (Fe–CN–Co) molecular switches can be obtained by controlling the crystallization temperature. Here, an intriguing conversion from Fe III –Co II to Fe II –Co III and back to Fe III –Co II upon increasing pressure at 200 K is rationalized.

Source: Inorganic Chemistry Frontiers

DOI: 10.1039/d4qi02499k

Authors: Buqin Xu, Yanling Li, Geoffrey Gontard, Keevin Béneut, Paraskevas Parisiades, Maxime Deutsch, Rodrigue Lescouëzec

Institutions: Centre National de la Recherche Scientifique, Sorbonne Université, Institut Parisien de Chimie Moléculaire, Institut de minéralogie, de physique des matériaux et de cosmochimie, Laboratoire de Cristallographie, Résonance Magnétique et Modélisations, Université de Lorraine

Language: English

Topic: Magnetism in coordination complexes

Subfield: Electronic, Optical and Magnetic Materials

Field: Materials Science

Domain: Physical Sciences

Open Access status: green

Funders: Université de Lorraine, Centre National de la Recherche Scientifique, Sorbonne Université

OpenAlex ID: W4404773073

FWCI: 0.389

Cites: 58

Cited by: 5

Related to: 10