Work

Eu3+- activated Sr2GdF7 colloid and nano-powder for horticulture LED applications

Year: 2024

Type: article

Abstract: A series of multifunctional Sr 2 Gd 1- x Eu x F 7 ( x = 0, 0.05, 0.10, 0.40, 0.60. 0.80, and 1.00) phosphors in stable colloidal form and as nanopowders have been prepared using a hydrothermal method. Powder X-ray diffraction analysis confirmed that the materials crystallize in a cubic crystal structure. Transmission electron microscopy shows quasi-spherical nanoparticles with an average particle size of ∼24 nm. Photoluminescence measurements show highly efficient red emission in both colloids and nanopowders, with intensity continually increasing up to 80 mol% of Eu 3+ content without concentration quenching. The most prominent emission peaks are around 600 nm (orange/red) and 700 nm (deep red), with the latter more pronounced. Quantum efficiency follows a similar trend, and reaches 60 % for the sample with 80 mol% of Eu 3+ content. In addition, similar asymmetry ratio values and CIE coordinates show that there is not a big change in the local symmetry around Eu 3+ ions or emission color across the series. This confirms that Eu 3+ resides in the same crystalline environment in samples. The observed 5 D 0 -level lifetimes gradually decrease from 12.0 ms to 6.9 ms as the Eu 3+ concentration increases. Judd-Ofelt parameters show slight variation with Eu 3+ concentration with Ω 4 always larger than Ω 2 . The temperature-dependent steady-state and time-resolved photoluminescence measurements demonstrate high stability of nanopowders’ emission up to 100 °C. The combination of temperature stability and high efficiency of emission, as well as the untypical dominant deep-red emission at 700 nm labels these nanoparticles as potential nanophosphors for various applications. • Synthesis of Eu 3+ -doped Sr 2 GdF 7 nanoparticles in both colloid and powder forms. • Cubic, quasi-spherical nanoparticles with an average particle size of ∼24 nm. • Efficient red-light output with unusually strong 5 D 0 → 7 F 4 emission at ∼700 nm. • Concentration quenching not being reached even at 80 % replacement of Gd 3+ by Eu 3+ . • T-dependent PL measurements demonstrate high stability of nanopowders’ emission.

Source: Journal of Alloys and Compounds

DOI: 10.1016/j.jallcom.2024.177820