Work

First Electrodeposition of Silicon on Crumbled MXene (c‐Ti3C2Tx) for High‐Performance Lithium‐Ion Battery Negative Electrode

Year: 2024

Type: article

Abstract: The demand for high energy density Li‐ion batteries requires electrode materials with high capacity and long cycling stability. Silicon is among the most promising negative electrode materials due to its high theoretical capacity, abundant resources, and low working potential. However, its poor conductivity and significant volume expansion during cycling limit its practical application. To overcome these issues, this study develops a two‐step synthesis method for a nanostructured composite based on silicon as the active material. First, a crumbled Ti3C2Tx (c‐Ti3C2Tx) structure formed through electrostatic interaction between a Ti3C2Tx suspension and 1 M KOH. Then, an amorphous silicon layer is electrodeposited onto the c‐Ti3C2Tx flakes in a room‐temperature ionic liquid, creating the Si/c‐Ti3C2Tx composite for the negative electrode of Li‐ion batteries. The c‐Ti3C2Tx structure enhances conductivity, provides mechanical stability to accommodate silicon's expansion, and offers nanostructured porosity for lithium‐ion diffusion. The composite material demonstrates exceptional cycling stability, achieving a capacity of 1300 mAh g−1 at C/5 with 91 % capacity retention after 100 cycles.

Source: Batteries & Supercaps

DOI: 10.1002/batt.202400633

Authors: Rehman Butt, Aleena Gigi, François Rabuel, Mathieu Morcrette, Jeremy Mallet