Work

Multi-amino functionalized triazine-based polymers as the catalyst for cycloaddition of CO2 to epoxides

Year: 2024

Type: article

Abstract: • Multiple-amino functionalized triazine-based polymer (MAFTP) were facilely synthesized and thoroughly characterized. • MAFTP/KI exhibited excellent catalytic performance as heterogeneous catalyst for CO 2 conversion into cyclic carbonates without the uses of transition metal or organic solvent. • MAFTP/KI showed superior recycling performance without catalytic activity decrease obviously for 5 runs, besides, it showed general applicability towards various substituted epoxide substrates. • DFT calculation was adopted to analyze the possible cycloaddition reaction mechanism, reactive site between MAFTP/KI and reactants, as well as the mechanism of CO 2 cycloaddition reaction were discussed. Designing efficient catalysts for CO 2 cycloaddition to reduce CO 2 emission is one of crucial for environmental issues technology. Herein, the multiple-amino functionalized triazine-based polymer (MAFTP) was prepared through the nucleophilic reaction of cyanuric chloride with melamine and ethylenediamine by a conventional heating method, which are favorable for CO 2 adsorption due to their nitrogen-rich structure. MAFTP was characterized entirely, the CO 2 adsorption capacity of MAFTP showed the CO 2 uptake performance with the values of 5.73 cm 3 g −1 at 273 K and 1 bar. MAFTP/KI catalyst exhibited efficient catalytic activity for CO 2 fixation to epoxides. 99 % propylene carbonate yield and 99 % selectivity were obtained under 120 °C, 2.0 MPa for 2.0 h without organic solvent. Additionally, the catalysts could be recycled easily from the products after reaction by centrifugation and then reused 5 times efficiently. Meanwhile, the catalytic activity of MAFTP/KI to other substituted epoxides was discussed. Moreover, DFT calculation was adopted to analyze the possible cycloaddition reaction mechanism. The MAFTP/KI system is a promising candidate for CO2 chemical fixation attributing to the low cost, abundant availability, easy separation and high catalytic activity for CO 2 chemical fixation.

Source: Molecular Catalysis

DOI: 10.1016/j.mcat.2024.114724

Authors: Chaokun Yang, Xin Wang, Xin Zhao

Institutions: Civil Aviation Flight University of China, Shenzhen University

Language: English

Topic: Carbon dioxide utilization in catalysis

Subfield: Process Chemistry and Technology

Field: Chemical Engineering

Domain: Physical Sciences

SDGs: Climate action, Responsible consumption and production

Open Access status: hybrid

Estimated APC paid: $3,110