Work

Influence of Copper Valence in CuOx/TiO2 Catalysts on the Selectivity of Carbon Dioxide Photocatalytic Reduction Products

Year: 2024

Type: article

Abstract: The Cu cocatalyst supported on the surface of TiO2 photocatalysts has demonstrated unique activity and selectivity in photocatalytic CO2 reduction. The valence state of copper significantly influences the catalytic process; however, due to the inherent instability of copper's valence states, the precise role of different valence states in CO2 reduction remains inadequately understood. In this study, CuOx/TiO2 catalysts were synthesized using an in-situ growth reduction method, and we investigated the impact of various valence copper species on CO2 photocatalytic reduction. Our results indicate that Cu+ and Cu0 serve as primary active sites, with the selectivity for CH4 and CO products during CO2 photoreduction being closely related to their respective ratios on the catalyst surface. The adsorption and activation mechanisms of CO on both Cu+ and Cu0 surfaces are identified as critical factors determining product selectivity in photocatalytic processes. Furthermore, it is confirmed that Cu+ primarily facilitates CH4 production while Cu0 is responsible for generating CO. This study provides valuable insights into developing highly selective photocatalysts.

Source: Nanomaterials

DOI: 10.3390/nano14231930

Authors: Sha Ni, Wenjing Wu, Zichao Yang, Min Zhang, Jianjun Yang

Institution: Henan University

Language: English

Topic: Advanced Photocatalysis Techniques

Subfield: Renewable Energy, Sustainability and the Environment

Field: Energy

Domain: Physical Sciences

Open Access status: gold

Estimated APC paid: $3,296

Funder: Natural Science Foundation of Henan Province