Rhodium( i )-catalyzed dearomative cycloisomerization of 1 H -indole N -tethered o -alkynylphenyl nitrones and application to spirocyclic pyrido[1,2- a ]indole synthesis
Year: 2024
Type: article
Abstract: A Rh( i )-catalyzed method to prepare indoline-fused polycyclic tropanes from 1 H -indole N -tethered o -alkynylphenyl nitrone cycloisomerization and their Ce( iv )-mediated dealkylative spirocyclization is described.
Source: Organic Chemistry Frontiers
DOI: 10.1039/d4qo01807a
Authors: Dandan Shang, Tianyu Lin, Yili Shen, Yongsheng Zhang, Philip Wai Hong Chan, Weidong Rao
Institutions: Nanjing Forestry University, Monash University
Language: English
Topic: Catalytic Alkyne Reactions
Subfield: Organic Chemistry
Field: Chemistry
Domain: Physical Sciences
Open Access status: green
Funder: Australian Research Council
OpenAlex ID: W4404941215