Work

Iodine-catalyzed 1-Aryltriazene/CS2 duo for sonochemical synthesis of 3-Sulphenylindoles employing [BMIM(SO3H)][OTf] as recyclable promoting system.

Year: 2024

Type: article

Abstract: Iodine-catalyzed regioselective sulphenylation of various 3-substituted indoles using CS 2 as potential tool is demonstrated. An efficient and eco-friendly protocol has been developed to synthesize libraries of 3-sulphenyl indoles by employing CS 2 as sulphur coupling-linkage for various 1-aryltriaznes and indoles. Short reaction time, mild reaction conditions, recycle and reuse of ionic liquids (ILs) are the advantages of this methodology. A plausible reaction mechanism to narrate the exploitation of the catalytic and promoting systems is also highlights of this work.

Source: Journal of Ionic Liquids

DOI: 10.1016/j.jil.2024.100128

Authors: Vinod Jadhav, Athmanand Anchi, Imamhusen Jamadar, Shruti S. Malunavar, Rajesh G. Kalkhambkar, Suraj M. Sutar

Institution: Karnatak University

Language: English

Topic: Sulfur-Based Synthesis Techniques

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

SDG: Responsible consumption and production

Open Access status: gold

Estimated APC paid: $1,200