Utilization of bentonite in cementation of Cs-137-contaminated electric arc furnace dust
Year: 2024
Type: article
Abstract: Cementation was employed to harden the Cs-137-contaminated electric arc furnace dust. The dust and cement were used as cementation binders. Bentonite was added to resist the Cs-137 leaching from the dust-cement-bentonite specimens. Various cementation recipes were used to prepare the specimens. The specimens cured for 28 days were subjected to the strength and leaching tests. The strength test was also performed on the leaching-tested specimens. The strengths of all specimens exceeded the acceptable level. The specimen strength dropped when the dust and/or bentonite were added. It could also decline due to the specimen component leaching. The amount of Cs-137 leached decreased as the bentonite content increased. The leachate Cs-137 concentration was positively correlated with the leachate pH and conductivity. The specimens without bentonite had Cs-137 leachability index (LI) values ranging from 6.2 to 6.8. The LI reduced as the dust content rose. The specimens containing bentonite had better LI values ranging from 6.6 to 9.3. The LI increased as the bentonite content increased. This proves that bentonite can be an effective cementation additive for retarding the Cs-137 leaching. The graph slopes revealed that the Cs-137 leaching was caused by diffusion or surface wash-off. However, the multiple mechanisms-based analysis using the leaching models showed that the Cs-137 leaching occurred as a result of the four processes (loosely bound Cs-137 release, surface wash-off, diffusion, and dissolution), with the insignificant contribution of diffusion.
Institution: Thailand Institute of Nuclear Technology
Language: English
Subfield: Safety, Risk, Reliability and Quality
Field: Engineering
Domain: Physical Sciences
Open Access status: gold
Estimated APC paid: $200
Award: G6694221341
OpenAlex ID: W4405024575