Work

Thermochemical investigation of phenyl and benzyl benzoates as lignin-based models for hydrogen storage

Year: 2024

Type: article

Abstract: The thermochemical properties of phenyl and benzyl benzoates, including vapour pressures, enthalpies of vaporisation and enthalpies of formation, were the subject of this study. The datasets for each thermodynamic property were evaluated using quantum chemical calculations and structure–property correlations and recommended for engineering calculations. The energetics of hydrogenation/dehydrogenation reactions relevant to hydrogen storage were calculated and compared with the enthalpies of reactions of conventional liquid organic hydrogen carriers. Graphical Abstract

Source: Journal of Thermal Analysis and Calorimetry

DOI: 10.1007/s10973-024-13765-6

Authors: Sergey P. Verevkin, Artemiy A. Samarov, Sergey V. Vostrikov

Institutions: Kazan Federal University, University of Rostock, St Petersburg University, Samara State Technical University

Language: English

Topic: Chemical Thermodynamics and Molecular Structure

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

SDG: Affordable and clean energy

Open Access status: hybrid

Estimated APC paid: $3,590