Work

Synthesis of (1-N-alkylnitramino)methoxy‑substituted oxetanes and oligomers based on them

Year: 2024

Type: article

Abstract: A number of functionalized (1-N-alkylnitramino)methoxy‑substituted oxetane derivatives have been synthesized using N-chloromethyl-N-alkylnitramines. The compounds were characterized using 1 H, 13 C and IR spectroscopy as well as elemental analysis of C, H, and N. The thermal behavior of the compounds was analyzed using differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). Based on individual representatives, a number of oligomers were synthesized and described to initially evaluate their potential. The oligomers were extensively characterized and common structural features were elucidated. These can be used to prepare useful energetic binders through cationic ring-opening polymerization.

Source: FirePhysChem

DOI: 10.1016/j.fpc.2024.12.002

Authors: Dmitry B. Vinogradov, Pavel V. Bulatov, Evgeny Yu. Petrov, Timur I. Mukhametshin, Tatiana V. Grinevich, Gulnaz M. Mukhametova

Institutions: Russian Academy of Sciences, N.D. Zelinsky Institute of Organic Chemistry, Kazan State Technological University, Semenov Institute of Chemical Physics

Language: English

Topic: Energetic Materials and Combustion

Subfield: Mechanics of Materials

Field: Engineering

Domain: Physical Sciences

Open Access status: diamond

OpenAlex ID: W4405283254

FWCI: 0.151

Cites: 36

Cited by: 1

Related to: 10