Work

Hexahalogenobismuthates of Glycine

Year: 2024

Type: conference-paper

Abstract: Five new glycine salts containing zero-dimensional BiX6 3− hexahalogeno-bismuthate anions were prepared: (GlyH)3(BiCl6)·2H2O (I) (space group Pna21, Z=4), (GlyH)3(BiBr6)·2H2O (II) (s.g. Cc, Z=4), (GlyH)3(BiBr6)·3H2O (III) (s.g. P21/n, Z=4), (GlyH)4(BiBr6)(Br)·H2O (IV) (s.g. P 1 ¯ , Z=2) and (GlyH)3(BiI6)·2H2O (V) (s.g. P21/n, Z=4). The (Gly+···Gly+) type centrosymmetric dimeric cation of glycine was observed for the first time in the structures (IV) and (V). Infrared spectra were registered and discussed. The bandgap values were calculated and measured.

Source: Journal of Physics Conference Series

DOI: 10.1088/1742-6596/2924/1/012012

Authors: Vahram V. Ghazaryan, Gerald Giester, Ashkhen L. Zatikyan, Gayane S. Tonoyan, Aram M. Petrosyan

Institutions: Institute of Applied Problems of Physics, University of Vienna, Yerevan State University

Language: English

Topic: Crystal structures of chemical compounds

Subfield: Inorganic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: diamond

OpenAlex ID: W4405318862

FWCI: 15.68

Cites: 11

Cited by: 4

Related to: 10