A zirconocene triazenido hydride complex activates CO 2
Year: 2024
Type: article
Abstract: led to the formation of a zirconocene(IV) triazenido-formate complex, which was further investigated for its stability towards different bases with respect to the formation of formic acid. The experimentally observed reaction pathway was investigated computationally using DFT methods, revealing the favourable role of pyridine coordination in the hydrogen transfer from the triazene to the alkyne unit of the zirconocene reagent.
Source: Dalton Transactions
DOI: 10.1039/d4dt03155e
Institutions: Leibniz Institute for Catalysis, University of Rostock
Language: English
Subfield: Organic Chemistry
Field: Chemistry
Domain: Physical Sciences
Open Access status: hybrid
Funder: Deutsche Forschungsgemeinschaft
OpenAlex ID: W4405337642