Substrate NOBINAc ligand affinity for Pd II -catalyzed enantioselective C–H activation over reactive β-C–H bonds in ferrocenyl amines
Year: 2024
Type: article
Abstract: an enhanced substrate ligand affinity. This approach resulted in a Pd-catalyzed enantioselective C-H activation, the first intermolecular annulation, and alkenylation of ferrocenyl amines with allenes and olefins, leading to ferrocene fused tetrahydropyridines and alkenylated ferrocenyl amines with up to 70% yields and 99 : 1 er.
Source: Chemical Science
DOI: 10.1039/d4sc06867j
Language: English
Subfield: Organic Chemistry
Field: Chemistry
Domain: Physical Sciences
Open Access status: diamond
Funders: Department of Science and Technology, Ministry of Science and Technology, India, Indian Institute of Science Education and Research Bhopal, Indian Institute of Science Education and Research Mohali, Science and Engineering Research Board, Science for Equity, Empowerment and Development Division, University Grants Commission - South Eastern Regional Office
OpenAlex ID: W4405365829