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Upconverting Nanoparticles and Cu(I) Complex-Based Platform for Oxygen Sensing, Thermometry, and Emission Color Tuning

Year: 2024

Type: article

Abstract: High Resolution Image Download MS PowerPoint Slide Multifunctional nanoplatforms combine different material properties to meet a wide range of applications, allowing highly customizable systems. In this rapidly advancing research field, we introduce a multifunctional nanomaterial based on the synergy between Tm 3+ -doped upconverting nanoparticles (UCNPs) and a Cu(I) complex (CuCom). This material is designed for oxygen sensing, optical thermometry, and emission color tuning. In various concentrations, the CuCom complex was electrostatically integrated into a mesoporous silica shell surrounding the core UCNPs (UCNP@mSiO 2 ). The optimized system, UCNP@mSiO 2 @CuCom-10, was evaluated for different applications. Due to the spectral overlap between the CuCom absorption and the nanoparticles emission, excitation at 980 nm allows most of the UV-blue emission output from the UCNPs to be transferred to the CuCom via luminescent resonance energy transfer (LRET), producing red emission from the molecule. The remaining Tm 3+ emission enables optical thermometry, while CuCom’s sensitivity to molecular oxygen supports its application in gas sensing. In upconversion mode, the nanoplatform achieved a Stern–Volmer constant for O 2 sensing of 1.64 and demonstrated thermometric relative sensitivities of 0.9% and 1% K –1 at room temperature, with a linear response from 193 to 373 K. Additionally, the emission color of UCNP@mSiO 2 @CuCom-10 can be tuned from blue to white and yellow, by varying the excitation and temperature, adding further functionality to the system. This multifunctional platform suggests promising applications in biology, medicine, and environmental monitoring.

Source: ACS Applied Nano Materials

DOI: 10.1021/acsanm.4c06351

Authors: Marylyn Setsuko Arai, Leandro Piaggi Ravaro, Gabriel Brambilla, Lauro June Queiroz Maia, Mohammad Reza Dousti, Andrea Simone Stucchi de Camargo