Work

Photolysis of bis (catecholato)silicates

Year: 2025

Type: article

Abstract: We investigated chemical consequences of direct irradiation of alkyl bis(catecholato)silicates. We provide evidence for alkyl radical formation through EPR spin-trapping experiments, relative kinetics of radical formation, as well as direct observation of nitro group stabilized semiquinone radical.

Source: The Journal of Organic Chemistry

DOI: 10.1021/acs.joc.4c03072

Authors: Mauricio Bahena Garcia, Victor Fadare, Ian Shire, Manvendra Singh, Samuel Figueroa-Lazú, Justin Douglas, Zarko Boskovic

Institutions: University of Kansas, Kansas Bureau of Investigation

Language: English

Topic: Electron Spin Resonance Studies

Subfield: Biophysics

Field: Biochemistry, Genetics and Molecular Biology

Domain: Life Sciences

Open Access status: green

Funders: National Science Foundation, National Institutes of Health, National Institute of General Medical Sciences, National Center for Research Resources, Division of Chemistry

Awards: G1909387548, Acquisition of a Multi-User EPR Spectrometer to Enhance Research and Teaching at Universities in the State of Kansas and Outreach Partner Universities in the Region, Avance II 500 High Performance Digital NMR Spectrometer System, AVIII HD 400 NMR spectrometer to replace existing DRX 400, Open access ESI-TOF/MS and GC/MS for organic chemists, G6882062388, MRI: Acquisition of a Multinuclear Broadband Cryogenically Cooled Probe for NMR Spectroscopy at KU-Lawrence, Chemical Biology of Infectious Disease

OpenAlex ID: W4408613761

FWCI: 0.749

Cites: 10

Cited by: 2

Related to: 10