Work

Mechanochemical generation of nitrogen-centred radicals for the formation of tertiary amines in polymers

Year: 2024

Type: article

Abstract: Carbamoylketoximes of N -pentenyl-substituted secondary amines give access to cyclic tertiary amine bases by a subsequent 5- exo-trig cyclization after homolytic bond scission of the mechanophore induced through polymer mechanochemistry.

Source: RSC Mechanochemistry

DOI: 10.1039/d4mr00099d

Authors: Sonja Storch, Davide Campagna, Simay Aydonat, Robert Göstl

Institutions: DWI – Leibniz Institute for Interactive Materials, RWTH Aachen University, University of Wuppertal

Language: English

Topic: Polymer composites and self-healing

Subfield: Polymers and Plastics

Field: Materials Science

Domain: Physical Sciences

Open Access status: diamond

Funders: Deutsche Forschungsgemeinschaft, Bundesministerium für Bildung und Forschung

Awards: Das Maßschneidern kraftinduzierter Reaktionspfade von Mechanophoren in Polymermaterialien durch energetischen Zustand und Richtungsabhängigkeit, Thermisch stabile optische Kraftsonden für technische hochperformante Polymermaterialien, Modellregion, Bio4MatPro: BoostLab 2-2 - MultiGlue, Multiselektives und -responsives Kleben, TP 1

OpenAlex ID: W4405552837

FWCI: 0.316

Cites: 55

Cited by: 3

Related to: 10