Multitopic Corannulene–Porphyrin Hosts for Fullerenes: A Three-Layer Scaffold for Precisely Designed Supramolecular Ensembles
Year: 2024
Type: article
Abstract: High Resolution Image Download MS PowerPoint Slide A method to synthesize cofacial dimeric porphyrins bearing eight corannulene units has been developed. It relies on the stability of octahedral CO-capped Ru(II) complexes linked by N-donor ligands. This specific arrangement provides an optimal scaffold to accommodate fullerenes by imposing corannulene groups at a precise distance and relative orientation. Their capabilities for C 60 recognition have been thoroughly assessed, revealing that each system can encapsulate up to four guests, giving rise to a compact supramolecular van der Waals complex echoing a discrete donor–acceptor–donor trilayer offering significant potential properties for further exploitation.
Source: Organic Letters
Institutions: Universidad de Valladolid, Universitat de Girona
Language: English
Subfield: Organic Chemistry
Field: Chemistry
Domain: Physical Sciences
Open Access status: hybrid
Estimated APC paid: $4,500
Awards: G1175115578, G121809054, G143639328, G145641598, G1639779852, G1855990336, G210041235, G2262748287, G2309174360, G2390397592, G2585926585, G2601397997, G2660406951, G279363373, G300979063, G3406072781, G34346518, G3480869486, G3518538256, G3681454997, G3824362713, G3899719709, G4042783231, G425668148, G430777504, G451871883, G4526231891, G464105488, G5080475149, G5195188938, G5389023829, G5421974903, G5700670944, G586857820, G654667917, G7017660613, G7084143925, G7391727506, G7434936867, G745419941, G8389516595, G8434830731, G846842501, G897484643, G99296377
OpenAlex ID: W4405622274