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Cover Feature: Thermochemistry of Solid‐State Formation, Structure, Optical, and Luminescent Properties of Complex Oxides Eu 2 MeO 6 (Me–Mo, W), Eu 2 W 2 O 9 : A Combined Experimental and DFT Study (Chem. Eur. J. 53/2024)

Year: 2024
Type: article
Abstract: Complex oxides Eu2MeO6 (Me=Mo, W) and Eu2W2O9 were obtained in a solid-phase reaction between binary oxides. The thermodynamic and kinetic mechanisms of the reaction processes were established by using a variety of physicochemical methods. Calculations of absorption spectra are shown to be superior to band structure analysis in the determination of optical band gaps. In this work, the experimental data are in good agreement with the theoretical models. More information can be found in the Research Article by Yu. G. Denisenko and co-workers (DOI: 10.1002/chem.202402084).
DOI: 10.1002/chem.202485302
Authors: Yulia V. Seredina, Aleksandr S. Oreshonkov, Maxim S. Molokeev, Alexander E. Sedykh, Aleksandr S. Aleksandrovsky, Maksim A. Zhernakov, Nikolay A. Khritokhin, Nikita O. Azarapin, Polina O. Glukhova, Natalia A. Shelpakova, Klaus Müller‐Buschbaum, Yuriy G. Denisenko
Institutions: University of Tyumen, Institute of Physics, Siberian Federal University, Justus-Liebig-Universität Gießen, Kazan Federal University, Industrial University of Tyumen
Language: English
Open Access status: bronze
OpenAlex ID: W4405694841
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