Organocatalytic CS 2 insertion into epoxides in neat conditions: a straightforward approach for the efficient synthesis of Di- and tri-thiocarbonates
Year: 2024
Type: article
Abstract: ) or tetrabutylammonium chloride (TBACl) is reported, for the first time, under solvent-free (neat) conditions. Fine-tuning of our system allowed us to obtain either dithiocarbonates (DTCs) or trithiocarbonates (TTCs) with high efficiency. Additionally, a mechanistic proposal is presented, supported by experimental evidence, DFT calculations and wavefunction analyses.
Source: Chemical Communications
DOI: 10.1039/d4cc05154h
Institutions: Universidad de Oviedo, ORFEO-CINQA Research Network
Language: English
Subfield: Process Chemistry and Technology
Field: Chemical Engineering
Domain: Physical Sciences
Open Access status: hybrid
OpenAlex ID: W4405696475