Shifting C 2 H 2 /CO 2 Adsorption and Separation in Pillar‐Layered Metal–Organic Frameworks Finely‐Regulated by Molecular Rotation
Year: 2024
Type: article
Abstract: The efficient separation of C₂H₂/CO₂ mixture is crucial for industrial applications. A promising strategy is proposed herein to fine‐tune the C₂H₂/CO 2 adsorption and separation by pillar‐layered metal–organic framework (MOF) adsorbents via molecular rotation. Keeping the same ultramicroporous architecture, three Zn‐X‐TRZ (TRZ = 1,2,4‐triazole) adsorbents are prepared with X‐pillar rotors varying from 9,10‐anthracenedicarboxylic acid (ADC), 1,4‐naphthalenedicarboxylic acid (NDC) to 1,4‐benzenedicarboxylic acid (BDC). Remarkably, the introduction of the largest ADC rotors enables Zn‐ADC‐TRZ with superior C₂H₂‐selective thermodynamic‐separation ability (highest heat of adsorption and IAST selectivity values) but poor dynamic‐separation performance caused by steric hindrance. Conversely, Zn‐BDC‐TRZ with the smallest rotors exhibit moderate CO₂‐selective thermodynamic‐separation ability, but excellent CO 2 /C₂H₂ dynamic‐separation ability with high‐purity C₂H₂ produced at 298 K (>99.5% obtained from 70% C₂H₂ mixture and >99.95% from 90% C₂H₂ mixture). In contrast, Zn‐NDC‐TRZ with medium NDC rotors shows comparable interactions and steric hindrance with C₂H₂ and CO₂, making both the thermodynamic and dynamic C₂H₂/CO₂ separation are unfavorable. Overall, controllable adsorption of C₂H₂ and CO 2 is successfully achieved and shifted from C 2 H 2 ‐selective to CO₂‐selective separation regulated by the pillared molecular rotation within pillar‐layered MOFs, providing a useful route for practical gas adsorbent exploration.
Source: Small
Authors: Li‐Qiu Yang, Ying Wang, Wen‐Yu Yuan, Quan‐Guo Zhai
Institution: Shaanxi Normal University
Language: English
Subfield: Inorganic Chemistry
Field: Chemistry
Domain: Physical Sciences
SDG: Climate action
Open Access status: bronze
OpenAlex ID: W4405698407