Work

Co(II)-Based 2D Coordination Polymer Featuring Energy Storage and Detection of Aqueous Inorganic Anions

Year: 2024

Type: article

Abstract: High Resolution Image Download MS PowerPoint Slide Herein, we have synthesized a Co(II)-based 2D coordination polymer [Co(5-AIA)(Imidazole)] n ( CP1 ) (AIA = 5-aminoisophthalic acid) via a solvothermal approach. SCXRD (single-crystal X-ray diffraction) was utilized to analyze the crystal structure of fabricated CP1 . Moreover, PXRD, TGA, FTIR, and SEM analyses were done to identify the structural features of fabricated CP1 . The standard rod depiction of CP1 exhibits hxl underlying net topology, and the hydrogen-bonded network depicts hcb underlying net topology. The fluorescence detection of inorganic anions using CP1 showed a promising result of 90.3% for MnO 4 – . The electrochemical analysis of CP1 was done under a basic medium utilizing a 3 M KOH electrolyte through CV (cyclic voltammetry) and GCD (galvanic charge–discharge) techniques which show a 134.75 F g –1 specific capacity at a current density of 1 A g –1 . Furthermore, CP1 shows a 94% retention capacity after 2500 cycles at a 20 A g –1 current density.

Source: ACS Omega

DOI: 10.1021/acsomega.4c08913

Authors: Basree, Arif Ali, Ganesh Chandra Nayak, Kafeel Ahmad Siddiqui, Musheer Ahmad

Institutions: Aligarh Muslim University, Indian Institute of Technology Dhanbad, National Institute of Technology Raipur

Language: English

Topic: Metal-Organic Frameworks: Synthesis and Applications

Subfield: Inorganic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: gold

Estimated APC paid: $1,935

Funders: National Institute of Technology, Raipur, Department of Science and Technology, Ministry of Science and Technology, India, University Grants Commission, Indian Institute of Technology (Indian School of Mines), Dhanbad