Work

Poly[diaqua[μ2-1,4-bis(pyridin-3-ylmethyl)piperazine][μ2-4-(2-carboxylatoethyl)benzoato]cobalt(II)]

Year: 2024

Type: article

Abstract: A layered cobalt coordination polymer containing both 4-(2-carboxylatoethyl)benzoate (ceb) and 1,4-bis(3-pyridylmethyl)piperazine (3-bpmp) ligands, [Co(C10H8O4)(C16H20N4)(H2O)2] n or [Co(ceb)(3-bpmp)(H2O)2] n , was isolated and structurally characterized by single-crystal X-ray diffraction. Chain-like [Co(ceb)(H2O)2] n units are oriented parallel to [101]. These are connected into (4,4)-grid coordination polymer layers by tethering 3-bpmp ligands. The layer motifs stack in an AAA pattern mediated by O—H...N hydrogen-bonding interactions between the aqua ligands in one layer and 3-bpmp piperazinyl N atoms in the abutting layer.

Source: IUCrData

DOI: 10.1107/s2414314624012252

Authors: Frederick C. Ezenyilimba, Robert L. LaDuca

Institution: Michigan State University

Language: English

Topic: Metal-Organic Frameworks: Synthesis and Applications

Subfield: Inorganic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: gold

Estimated APC paid: $300

Funders: Michigan State University, College of Engineering, Michigan State University, Lyman Briggs College, Michigan State University