Year: 2024
Type: article
Abstract: Comprehensive Summary The invention of novel linkers is a long‐lasting task in the area of the sulfur(VI) fluoride exchange reaction (SuFEx). Compared with the most frequently investigated sulfonyl fluorides, synthetic accessibility toward its mono‐aza isostere, i.e., sulfonimidoyl fluorides is still limited. Herein, we report an electrochemical carbonfluorination of the readily available N‐sulfinylamines to access various aryl and alkyl sulfonimidoyl fluorides. The transformation is characterized by the ready availability of starting materials, mild reaction conditions, and obviating metal catalysts and chemical oxidants.
Source: Chinese Journal of Chemistry
Authors: Fang‐Ling Gao, Xinglei He, Bin Zhao, Yuqi Lin, Ke‐Yin Ye
Institutions: Fuzhou University, Henan Normal University
Language: English
Subfield: Organic Chemistry
Field: Chemistry
Domain: Physical Sciences
Open Access status: bronze
OpenAlex ID: W4405813814