Work

MA-activated lattice shrinkage and bandgap renormalization advancing the stability of FA1-MA PbI3 (x=0–1) perovskites photovoltaic

Year: 2024

Type: article

Abstract: Generally, referring to the stability of perovskite, the most studied perovskite material has been MA-free mixed-cation perovskite. The precise role of MA in the light-thermal-humid stability of perovskite solar cells still lacks of a systematically understanding. In this work, the evolution of crystallographic structures, intermediate phase, ultrafast dynamics, and thermal decomposition behavior of MA-mixed perovskite FA 1- x MA x PbI 3 ( x =0–100%) are investigated. The influence of MA on the stability of devices under heat, light, and humidity exposure are revealed. In the investigated compositional space ( x =0–100%), device efficiencies vary from 19.5% to 22.8%, and the light, thermal, and humidity exposure stability of the related devices are obviously improved for FA 1- x MA x PbI 3 ( x =20%–30%). Incorporation 20%–30% of MA cations lowers nucleation barrier and causes a significant volume shrinkage, which enhances the interaction between FA and I, thus improving crystallization and stability of the FA 1- x MA x PbI 3 . Thermal behavior analysis reveals that the decomposition temperature of FA 0.8 MA 0.2 PbI 3 reaches 247 °C (FAPbI 3 , 233 °C) and trace amounts of MA cations enhance the thermal stability of the perovskite. Remarkably, we observe lattice shrinkage using spherical aberration corrected transmission electron microscope (AC-TEM). This work implies that stabilizing perovskites will be realized by incorporating trace amounts of MA, which improve the crystallization and carrier transport, leading to improved stability and performances. The evolution of crystallographic structures, intermediate phase, ultrafast dynamics and thermal decomposition behavior of MA-mixed perovskite (FA 1-x MA x PbI 3 , x = 0%–100%) were systematically investigated. MA incorporation improves the stability of the perovskite by enhancing interactions between FA and I through shrinkage of the cubo-octahedral volume. This work has important implications for the control of A-site cations and the design of more stable perovskite structures on a microscopic scale. • Trace of MA + in FA 1-x MA x PbI 3 lowers nucleation barriers and improves thermal stability of FA 1-x MA x PbI 3 compared to FAPbI 3 . • The lattice shrinkage caused by MA + substitution is the origins of enhanced light-thermal humid stability of device. • MA + induces obvious bandgap renormalization in FA 1-x MA x PbI 3 , increasing electron effective mass.

Source: Advanced Powder Materials

DOI: 10.1016/j.apmate.2024.100264