Work

Visible-light-promoted phosphorylation carbonylation of unactivated alkenes

Year: 2024

Type: article

Abstract: Phosphorus-containing compounds represent a class of chemicals of great significance. Therefore, it is of high value to develop efficient C-P bond formation methods. However, the activity of phosphoryl radicals results in the facile formation of hydrophosphination products when difunctionalized carbonylation was performed with the addition of alkenes . In this study, we presented a visible light-promoted phosphorylation carbonylation reaction of unactivated alkenes . Both visible light catalyst and oxidant-promoted generating phosphoryl radical from diarylphosphine oxide, which subsequently adding to unactivated alkenes and followed by intramolecular migration in the presence of carbon monoxide to yield the targeted phosphorus-containing carbonyl compounds .

Source: Journal of Catalysis

DOI: 10.1016/j.jcat.2024.115933

Authors: Ren-Guan Miao, Yuanrui Wang, Xiao-Feng Wu

Institutions: Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Leibniz Institute for Catalysis, Dalian National Laboratory for Clean Energy, University of Chinese Academy of Sciences

Language: English

Topic: Radical Photochemical Reactions

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: hybrid

Estimated APC paid: $3,910

Funders: Dalian Institute of Chemical Physics, National Key Research and Development Program of China