Development and Characterization of Biomass-Derived Carbons for the Removal of Cu2+ and Pb2+ from Aqueous Solutions
Year: 2024
Type: article
Abstract: This research explores the synthesis and application of carbon-based adsorbents derived from olive stones and almond shells as low-cost biomass precursors through carbonization at 600°C combined with chemical activation using KOH, H3PO4 and ZnCl2 with carbon/activating agent (C/A) ratios of 1:2 and 1:4 (w/w) at 850°C for the removal of Cu2+ and Pb2+ ions from aqueous solutions. The carbons produced were characterized using different techniques including SEM-EDX, FTIR, XRD, BET analysis, CHNS elemental analysis and point of zero charge determination. Batch-mode adsorption experiments were carried out at adsorbent doses of 2 and 5 g L-1, initial metal concentrations of 100 and 500 mg L-1 and natural pH (around 5) with agitation at 350 rpm and 25°C for 24 h. KOH-activated carbons, especially at a 1:4 (w/w) ratio, exhibited superior adsorption performance mainly due to their favorable surface characteristics and functionalities. The greatest adsorption efficiency reached 100% (101.41-101.68 mg g-1) for Pb2+ at 500 mg L-1 and 5 g L-1 dosage, and 84.63-86.29% (41.69-42.52 mg g-1) for Cu2+ at 100 mg L-1 and 2 g L-1 dosage. The results of this study will help advance knowledge in the design and optimization of adsorption processes for heavy metal removal, benefiting industries seeking green technologies to mitigate environmental pollution.
Source: C – Journal of Carbon Research
DOI: 10.3390/c11010002
Institution: Universidade de Santiago de Compostela
Language: English
Subfield: Water Science and Technology
Field: Environmental Science
Domain: Physical Sciences
Open Access status: gold
Estimated APC paid: $1,819
Funder: Agencia Estatal de Investigación
OpenAlex ID: W4405954441