Work

Engineering mechanisms of proton-coupled electron transfer to a titanium-substituted polyoxovanadate–alkoxide

Year: 2025

Type: article

Abstract: The mechanism of proton-coupled electron transfer at the surface of titanium-substituted polyoxovanadate-alkoxide clusters can be tuned by judicious selection of substrate.

Source: Chemical Science

DOI: 10.1039/d4sc06468b

Authors: Shannon E. Cooney, S. Genevieve Duggan, M. Rebecca A. Walls, Noah J. Gibson, James M. Mayer, Pere Miro, Ellen M. Matson

Institutions: University of Rochester, University of Iowa, University of South Dakota, Yale University

Language: English

Topic: Polyoxometalates: Synthesis and Applications

Subfield: Materials Chemistry

Field: Materials Science

Domain: Physical Sciences

Open Access status: diamond

Funders: National Science Foundation, Camille and Henry Dreyfus Foundation, Yale University, University of South Dakota, Division of Chemistry

Awards: G1185160924, G3677039625, G4395575726, G5986892838, MRI: Acquisition of the Lawrence Supercomputer to Advance Multidisciplinary Research in South Dakota, G6671297155, G6884065497, CAREER: Understanding Structure-Function Relationships of Polyoxovanadate-Alkoxide Clusters from a Bottom-Up Perspective, CAS: Synthesis and Reactivity of Oxygen-atom Vacancies in Molecular Vanadium Oxide Assemblies, Fundamental Redox Reactivity at Binary Nanoparticle/Solution Interfaces

OpenAlex ID: W4406130516

FWCI: 1.696

Cites: 62

Cited by: 8

Related to: 10