Ni12P5 and Ni12P5-rGO for multifunctional electrocatalyst and supercapacitor application
Year: 2025
Type: article
Abstract: Transition metal phosphides are crucial for various environmental and energy applications. In this study, porous Ni 12 P 5 and Ni 12 P 5 -rGO were synthesized using a one-step solvothermal method. Red phosphorus served as the phosphorus source, while ethylene glycol acted as a capping agent to promote the formation of nanomaterials within a nitrogen-rich atmosphere. The catalytic performance of these materials was evaluated through their hydrogen evolution reaction (HER), oxygen evolution reaction (OER), and capacitance properties. Notably, Ni 12 P 5 -rGO exhibited Tafel slopes of 66 mV/dec for OER and 33 mV/dec for HER, indicating enhanced charge transfer efficiency compared to Ni 12 P 5 , which showed slopes of 78 mV/dec and 102 mV/dec, respectively. This improvement suggests that Ni 12 P 5 -rGO facilitates faster electron transfer, resulting in superior catalytic performance. Additionally, the synergistic effect of reduced graphene oxide (rGO) contributes to improved charge storage capabilities. The Ni 12 P 5 -rGO demonstrated a specific capacitance of 192 F/g, significantly higher than the 110 F/g observed for Ni 12 P 5 at a current density of 1 A/g. Remarkably, these materials maintained their capacity over 5000 cycles, achieving a commendable 98 % coulombic efficiency. These findings highlight the potential of Ni 12 P 5 -rGO as an effective material for energy conversion and storage applications, showcasing its promising role in advancing the efficiency of related technologies.
Source: Heliyon
Institution: Pittsburg State University
Language: English
Field: Energy
Domain: Physical Sciences
Open Access status: gold
Estimated APC paid: $2,270
OpenAlex ID: W4407065084