Work

Vertically aligned carbon nanotubes from premade binary metal oxide nanoparticles on bare SiO2

Year: 2025

Type: article

Abstract: The synthesis of carbon nanotubes (CNTs) requires well-defined catalyst nanoparticles that can influence both diameter and chirality. Herein, catalyst nanoparticles containing both the catalyst and catalyst support material were developed. Binary-metal oxide (AlO x –Fe 2 O 3 ) nanoparticles was synthesized from a mixture containing both aluminum and iron oleate precursors in the solution phase. The nanoparticles were assembled as a monolayer film on a silicon oxide (SiO 2 ) substrate via organic linker molecules to synthesize vertically aligned carbon nanotubes (VA-CNTs). Microscopic and spectroscopic characterization of the premade catalyst nanoparticles and monolayer film assembly revealed the quality of the nanoscale assembly, which facilitated the successful growth of VA-CNTs. The length of the CNTs synthesized using these AlO x –Fe 2 O 3 nanorice catalyst nanoparticles surpassed that of previously reported CNTs grown on bare SiO 2 surfaces without oxide buffer layers. In addition, the CNTs appeared to be directly bonded/connected to the SiO 2 substrate, suggesting CNT formation via the tip-growth mechanism. The effects of growth temperature and catalyst reduction time were evaluated to obtain high-yield VA-CNTs.

Source: Carbon

DOI: 10.1016/j.carbon.2025.120086

Authors: Abdul Hoque, Chaminda P. Nawarathne, Noe T. Alvarez

Institution: University of Cincinnati

Language: English

Topic: Carbon Nanotubes in Composites

Subfield: Materials Chemistry

Field: Materials Science

Domain: Physical Sciences

Open Access status: hybrid

Estimated APC paid: $4,830

Funders: National Science Foundation, Division of Materials Research, Division of Industrial Innovation and Partnerships