Work

Developing orbital-dependent corrections for the non-additive kinetic energy in subsystem density functional theory

Year: 2025

Type: article

Abstract: We present a novel route to constructing cost-efficient semi-empirical approximations for the non-additive kinetic energy in subsystem density functional theory. The developed methodology is based on the use of Slater determinants composed of non-orthogonal Kohn-Sham-like orbitals for the evaluation of kinetic energy expectation values and the expansion of the inverse molecular-orbital overlap matrix into a Neumann series. By applying these techniques, we derived and implemented a series of orbital-dependent approximations for the non-additive kinetic energy, which are employed self-consistently. Our proof-of-principle computations demonstrated quantitatively correct results for potential energy curves and electron densities and hinted on the applicability of the introduced empirical parameters to different types of molecular systems and intermolecular interactions. Therefore, we conclude that the presented study is an important step toward constructing accurate and efficient orbital-dependent approximations for the non-additive kinetic energy applicable to large molecular systems.

Source: The Journal of Chemical Physics

DOI: 10.1063/5.0241361

Authors: Larissa Sophie Eitelhuber, Denis G. Artiukhin

Institution: Freie Universität Berlin

Language: English

Topic: Advanced Chemical Physics Studies

Subfield: Atomic and Molecular Physics, and Optics

Field: Physics and Astronomy

Domain: Physical Sciences

Open Access status: hybrid

Estimated APC paid: $3,500

Funder: Deutsche Forschungsgemeinschaft