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mer-[InCl3(C5D5N)3]2·C5D5N: A New d5-pyridine Derivative of Indium(III) Chloride Complex

Year: 2025

Type: article

Abstract: In this study, we report the crystal structure of a meridional octahedral pyridine-indium(III) chloride adduct, mer-trichlorotris(d5-pyridine)indium(III)·0.5(d5-pyridine), InCl3(C5D5N)3·0.5(C5D5N), which exhibits an unreported molecule-to-solvent ratio compared to other substituted and unsubstituted pyridine-indium(III) chloride adducts described in earlier literature. The bonding characteristics of this d5-pyridine complex are compared to analogous complexes that have already been reported. Furthermore, the role of this metal complex in indium insertion into corrole ligands is discussed.

Source: Journal of the Turkish Chemical Society Section A Chemistry

DOI: 10.18596/jotcsa.1590991

Authors: Ali Tuna, Anastassios Papageorgiou, Anssi Peuronen, Pekka Peljo, Günther Knör

Institution: University of Turku

Language: English

Topic: Crystal structures of chemical compounds

Subfield: Inorganic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: diamond

Funders: Turun Yliopisto, Universität Zürich, Biocenter Finland, Division of Materials Research

OpenAlex ID: W4407178023

FWCI:

Cites: 17

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Related to: 10