Work

Microwave Activation of the [FeCl3·6H2O–TsOH·H2O]-Catalyzed Reaction of Norbornene with Organic Nitriles

Year: 2024

Type: article

Abstract: An efficient catalytic system consisting of 20 mol % FeCl 3 ·6H 2 O and 20 mol % of p -toluenesulfonic acid has been proposed for the amidation of norbornene in toluene with organic nitriles under microwave irradiation at 95°C for 1 h. The corresponding N -(norbornan-2- exo -yl) carboxamides have been obtained with high yields. The efficiency of InCl 3 in the amidation of norbornene with aryl cyanides has been demonstrated for the first time.

Source: Russian Journal of Organic Chemistry

DOI: 10.1134/s107042802412008x

Authors: K. S. Frolova, T. P. Zosim, I. R. Ramazanov

Institutions: Russian Academy of Sciences, Institute of Catalysis and Petrochemistry

Language: English

Topic: Microwave-Assisted Synthesis and Applications

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: hybrid

Funders: Russian Science Foundation, Russian Academy of Sciences

Award: G6620549873