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Novel poly(ether sulfone isopropyl sulfide) support layer in thin film composite membrane for desalination

Year: 2025
Type: article
Abstract: • Novel high molecular weight polysulfone terpolymer and similar blend were prepared. • Porous support layers were prepared via phase inversion of cast polymer. • TFC was obtained through interfacial polymerization of polyamide on support layers. • Performance of resulting TFC from random terpolymer was superior to other samples. • 97% Salt rejection and 92% flux recovery ratio was obtained for terpolymer. The aim of this research was to design a new polysulfone for the support layer of thin film composite (TFC) membranes and compare it with commercial structures for desalination applications. Accordingly, a novel random terpolymer was synthesized using the polycondensation reaction of bisphenol A and thiodiphenol with dichlorodiphenyl sulfone, comprising both methyl and sulfide groups in the backbone of the polymer. Subsequently, three asymmetric support layers were prepared using: the terpolymer, a polymer blend based on commercial polysulfone and a sulfide-containing polysulfone, and commercial polysulfone. Next, TFCs were prepared through the interfacial polymerization of polyamide on aforementioned support layers. Characterization was performed using 1 H NMR, FTIR, GPC, tensile test, water contact angle, DSC, TGA, SEM, ATR-FTIR, AFM, and zeta potential analyses. M w , Young's modulus, and contact angle of prepared terpolymer were 88,000 g.mol −1 , 3684 MPa, and 59˚ which were predominant properties in respect to commercial polysulfone with 66,000 g.mol −1 , 2541 MPa, and 73˚ values, respectively. AFM analysis showed that the mean difference between the highest peaks and lowest valleys increased from 79 nm for commercial polysulfone to 219 nm for synthesized terpolymer. Finally, superior performance was observed for the terpolymer-based TFC with 97% NaCl rejection and excellent 91.8% saline solution flux recovery when tested against NaCl salt and BSA as a natural biofoulant. Long-term stability of water flux and salt rejection were observed as well, reaching ∼ 27 L.m −2 .h −1 and 97.5% values, respectively. The results indicated that this terpolymer could be a promising substitute for commercial polysulfone in water purification membranes.
DOI: 10.1016/j.ceja.2025.100717
Language: English
Open Access status: gold
Estimated APC paid: $2,050
OpenAlex ID: W4407320409
FWCI: 1.276
Cites: 136
Cited by: 5
Related to: 10