Work

Optimization of redox-mediated electrodialysis systems for efficient water softening: Enhanced removal of calcium and magnesium ions

Year: 2025

Type: article

Abstract: Redox-mediated electrodialysis (redox-ED) is one of the most advanced electrochemical ion removal technologies, offering continuous and efficient ion removal. Although advantageous over previous systems, comprehensive assessments of its ion removal performance and the influence of operational parameters are scarce. This study optimized a scaled-up redox-ED cell for the removal of calcium (Ca²⁺) and magnesium (Mg²⁺) ions, targeting water softening applications, and evaluated its electrochemical performance. Under optimal conditions, the system achieved a charge efficiency exceeding 75% and a total hardness removal rate of over 95%, with reasonable energy consumption. Specifically, the removal rates for Ca²⁺ and Mg²⁺ were 90.5% and 90.8%, respectively, demonstrating the system's feasibility for use in water softening modules. Key factors affecting performance were scrutinized, revealing increased internal resistance as a significant hurdle. Furthermore, the integration of conductive ion exchange resins within the feed channel notably improved Ca²⁺ and Mg²⁺ removal rates, underscoring the potential of the redox-ED system in water softening applications.

Source: Environmental Engineering Research

DOI: 10.4491/eer.2024.692

Authors: Junghun Lee, Mingyu Park, Sung Pil Hong, Ki-Myeong Lee, Changha Lee

Institutions: Seoul National University, Institute of Engineering Research, Samsung Electronics (South Korea)

Language: English

Topic: Membrane-based Ion Separation Techniques

Subfield: Biomedical Engineering

Field: Engineering

Domain: Physical Sciences

SDG: Clean water and sanitation

Open Access status: diamond

Funders: Ministry of Trade, Industry and Energy, Samsung, Korea Evaluation Institute of Industrial Technology