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Multigram-Scale Synthetic Routes to Solvent-Free Common Secondary Dialkylphosphines and Chlorodialkylphosphines

Year: 2025

Type: article

Abstract: High Resolution Image Download MS PowerPoint Slide Secondary dialkylphosphines and chlorodialkylphosphines are some of the most common starting points in ligand synthesis; however, sourcing these synthons can be troublesome. In this paper, we present scalable synthetic routes to the iso -propyl, tert -butyl, and cyclohexyl derivatives. Detailed experimental procedures are given to allow for ease of synthesis.

Source: Organometallics

DOI: 10.1021/acs.organomet.4c00508

Authors: Amanda A. Fogh, Sara Belazregue, Andrew E. Ashley, F. Mark Chadwick

Institution: Imperial College London

Language: English

Topic: Organophosphorus compounds synthesis

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: hybrid

Estimated APC paid: $4,500

OpenAlex ID: W4407777104

FWCI: 2.615

Cites: 38

Cited by: 9

Related to: 10