Work

Enhanced Piezoelectric Performance of Highly-Aligned ZnO Nanorods Embedded in P(VDF-TrFE) Nanofiber Membranes

Year: 2025

Type: article

Abstract: Flexible and wearable electronics often rely on piezoelectric materials, and Poly(vinylidene fluoride-trifluoroethylene) (P(VDF-TrFE)) membranes are popular for this application. However, their electromechanical performance is limited due to a relatively low piezoelectric coefficient. To address this, this study investigates the incorporation of zinc oxide (ZnO) nanorods (NRs) into a P(VDF-TrFE) nanofiber membrane matrix. ZnO NRs were synthesized and doped into well-aligned P(VDF-TrFE) nanofibers using electrospinning with a high-speed rotating drum. The impact of ZnO NRs' mass fraction on the piezoelectric properties of the membranes was evaluated. Results show that a maximum piezoelectric coefficient (d33) of -62.4 pC/N, 9.5 times higher than neat P(VDF-TrFE), was achieved. These enhanced membranes demonstrated excellent performance in finger-tapping and bending detection, making them promising for large-scale flexible sensor applications in wearable electronics. This approach offers a simple and effective route to improve the performance of piezoelectric materials in flexible devices.

Source: Polymers

DOI: 10.3390/polym17050585