Work

Thermal performance evaluation of recycled salt hydrates through T-history

Year: 2025

Type: article

Abstract: Recycled magnesium sulfate heptahydrate, sourced from chemical byproducts in the nano-silica extraction from olivine, exhibits unique minor phases and reduced purity compared to analytical-grade counterparts. This study investigates phase stabilizer usage, titania as a nucleating agent, and carboxymethyl cellulose (CMC) as a stabilizing gel, to enhance the functionality of recycled salt hydrates for thermal energy storage applications. Thermocouple measurements over ten heating and cooling cycles reveal distinct thermal characteristics, with observable latent heat manifesting as a critical indicator for melting-crystallization cycling. The addition of titania increases the number of functional cycles of recycled samples but diminishes performance in analytical samples. Suggesting it provides another function other than nucleation. Statistical analysis shows an exponential decay in thermal cycles (R 2 > 0.84) with increased cycles. While titania shows promise, gel stabilizers like CMC did not yield meaningful results. The average latent heat storage of the recycled epsomite was 285.4 ± 37.1 J/g. This study addresses a previously unexplored area and highlights the potential of nucleating agents in improving the functionality of recycled salt hydrates for sustainable thermal energy storage.

Source: Case Studies in Thermal Engineering

DOI: 10.1016/j.csite.2025.105961

Authors: Charles A. Wesemann, Tessa Junggeburth, H.J.H. Brouwers

Institution: Eindhoven University of Technology

Language: English

Topic: Adsorption and Cooling Systems

Subfield: Mechanical Engineering

Field: Engineering

Domain: Physical Sciences

SDGs: Responsible consumption and production, Affordable and clean energy

Open Access status: gold

Estimated APC paid: $1,620