Work

Refractive indices of binary mixtures of diglycolamine - water at various temperatures

Year: 2025

Type: article

Abstract: In this work, the refractive indices n D , refractive index deviations Δ n D , molar refractions R m and excess molar refractions R E m were determined over the full range of compositions for the Diglycolamine-water binary mixture. Experimental measurements of these properties were carried out at atmospheric pressure and at temperatures ranging from 293.15 to 333.15 K. Excess molar refractions R E m and refractive index deviations Δ n D have been fitted to the polynomial Redlich-Kister equation. The refractive indices have been compared with those predicted by the mixing rules proposed by: Lorentz-Lorenz (L-L), Gladstone- Dale (G-L), Eykman (E), Arago-Biot (A-B), Eyring-John (E-J), Bruggeman (B), and Oster (OS), in order to verify their validity for the Diglycolamine-water binary system. The experimental values of the refractive indices agree well with all the previous relationships, with the relationship of Oster (OS) and Gladstone-Dale (G-L) with which better results are obtained.

Source: Chemical Thermodynamics and Thermal Analysis

DOI: 10.1016/j.ctta.2025.100179

Author: Eduardo I. Concepción

Institution: Universidad Tecnológica de Panamá

Language: English

Topic: Thermodynamic properties of mixtures

Subfield: Fluid Flow and Transfer Processes

Field: Chemical Engineering

Domain: Physical Sciences

Open Access status: gold

Estimated APC paid: $1,350

Funders: Secretaría Nacional de Ciencia, Tecnología e Innovación, Sistema Nacional de Investigadores