Ligand Deprotonation and Spin Crossover in Fe(II) Complex
Year: 2025
Type: article
Abstract: The effect of deprotonation of the hydrazine-based ditopic isomeric terpyridine-like ligand on the spin crossover behavior of the Fe(II) complex is studied. The deprotonation is modelled by the appearance of a negative charge on the nitrogen ions from the first coordination sphere of the iron ion. It is demonstrated that depending on the distribution of this negative charge on the nitrogen ions, deprotonation can either prevent or facilitate spin conversion.
Source: Physics of the Solid State
Authors: S. Ostrovsky, S. Klokishner
Institutions: Moldova State University, Institute of Applied Physics
Language: English
Field: Materials Science
Domain: Physical Sciences
Open Access status: diamond
OpenAlex ID: W4408062881