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Palladium–Catalyzed α‐Arylation of Sulfoxonium Ylides with Aryl Thianthrenium Salts via C−S and C−H Bond Activation

Year: 2025

Type: article

Abstract: Diverse α-aryl α-carbonyl sulfoxonium ylides were efficiently synthesized in yields ranging from moderate to high via a palladium-catalyzed α-arylation of sulfoxonium ylides with aryl thianthrenium salts. The reactions proceeded smoothly via C-S and C-H bond functionalization, exhibiting broad substrate scope and good compatibility to various functionalities. In addition, the scale-up synthesis could be achieved, and the one-pot protocol commencing from the use of simple arene as the precursor of aryl thianthrenium salt could also be accomplished.

Source: Chemistry - An Asian Journal

DOI: 10.1002/asia.202401873

Authors: Qing‐Dong Wang, Xue Chen, Yuan‐Shuai Wu, Chengping Miao, Jin‐Ming Yang, Zhi‐Liang Shen

Institutions: Yancheng Teachers University, Nanjing Tech University, Jiaxing University

Language: English

Topic: Catalytic C–H Functionalization Methods

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: bronze

Funders: Yancheng Teachers University, Nanjing Tech University

OpenAlex ID: W4408070370

FWCI: 2.98

Cites: 146

Cited by: 10

Related to: 10