Work

The New Paradigm Caused by Regulation (EU) 2024/1252 on the Upcycling of Landfilled Ferrous Slags—Case Study: Iron and Steel Slag Dumps in Romania

Year: 2025

Type: article

Abstract: Romania has some huge ferrous slag stockpiles that are secondary resources of minerals. Although a sizable portion of ferrous slags is recycled for use in building roads and other infrastructure, a sizable portion is still dumped. By November 2026, Member States must submit information on the quantity of critical raw materials (CRMs) in their secondary resources, as well as the quantification techniques employed, in accordance with Regulation (EU) 2024/1252. Therefore, the XRFS reliable measurements carried on ferrous slags were addressed to prevent dissipative loss of CRMs in cases where an improper slag recycling route is operated. The main novelty of this paper is the method of ensuring the reliability of the XRFS results based on weighted arithmetic mean and on the maximum likelihood approach. Secondly, the XRFS measurements carried on ferrous slags demonstrate that they contain CRMs like Ba, Sr, Y, etc.; however, below the minimum cut-off grade for CRMs, recovery XRFS cannot detect light CRMs. Our preliminary LIBS measurements on ferrous slags disclosed the presence of Li and Be. The drawbacks of the XRFS technique impose further research to develop an integrated XRFS, LIBS, and XRD procedure for comprehensive and trustworthy CRMs screening in extractive waste piles.

Source: Minerals

DOI: 10.3390/min15030260